The Complete Guide to Nylon Grades: PA6, PA66, PA11, PA12 and More

PA6, PA66, PA11, and PA12 nylon pellets and molded parts arranged for grade selection
Choosing the right nylon grade is critical for engineering success

Nylon grades are selected in two steps: first choose the PA matrix, such as PA6, PA66, PA11, or PA12; then choose whether it remains unfilled or receives glass fiber, carbon fiber, impact, flame-retardant, wear, or other modification.

For the main commercial routes, unfilled PA is the baseline, GF20 adds moderate structural reinforcement, and CF30 targets higher specific stiffness or special electrical and dimensional requirements. The highest fiber percentage is not automatically the best grade.

Nylon Grade Selection at a Glance

First Decision Common Starting Point Reason
General molded part Unfilled PA6 or PA66 Toughness, wear, and processing balance
Moderate deflection control PA-GF20 More stiffness with a broader balance than higher loading
Structural molded part PA-GF30 Common stiffness and dimensional-control route
High specific stiffness or ESD review PA-CF30 Weight, low CTE, or electrical formulation requirements
Wet dimensional service PA12 or qualified modified grade Lower moisture uptake

The Nylon Family Overview

Grade Type Melting Point Moisture (50% RH) Key Characteristic
PA6 Aliphatic 220°C 2.7% Toughness, processability
PA66 Aliphatic 260°C 2.5% Strength, heat resistance
PA11 Bio-based 185°C 0.8% Flexibility, low moisture
PA12 Aliphatic 178°C 0.7% Lowest moisture absorption
PA46 Aliphatic 295°C 3.5% Highest heat resistance
Nylon grade comparison chart
Each nylon grade fills a specific performance niche

PA6: The Versatile Workhorse

PA6 is the most widely used nylon grade, representing approximately 60% of nylon consumption. It offers an excellent balance of strength, toughness, and processability.

Key Properties

  • Tensile strength: 70-85 MPa
  • Excellent impact resistance
  • Good surface finish and colorability
  • Wider processing window than PA66

PA66: The High-Performance Standard

PA66 applications in automotive
PA66 dominates under-hood automotive applications

PA66 offers approximately 10-15% higher strength and stiffness than PA6, with superior heat resistance. It’s the preferred choice for demanding applications.

PA11 and PA12: The Specialty Nylons

PA11 and PA12 are distinguished by their exceptionally low moisture absorption—less than 1% even at saturation. This gives them outstanding dimensional stability.

PA11 and PA12 applications
PA11 and PA12 excel in chemical resistance and dimensional stability

PA46: The High-Temperature Specialist

PA46 (Stanyl) offers the highest heat resistance of any aliphatic nylon, with a melting point of 295°C.

Base Resin and Reinforcement Are Separate Decisions

PA6-GF20 and PA66-GF20 share the same glass percentage but not the same moisture response, melting range, heat capability, or processing window. The same applies to PA6-CF30, PA66-CF30, and PA12-CF30. Drawings and purchase orders should identify the complete matrix and modification package.

  • Unfilled PA: prioritize toughness, fatigue, wear, surface quality, and easier processing.
  • GF20: use when moderate stiffness and lower shrinkage are needed without moving directly to a higher glass loading.
  • GF30: use for a common structural balance, with gate, weld-line, and warpage review.
  • CF30: use when specific stiffness, low thermal expansion, weight, or an electrical target justifies the premium and processing controls.

Selection Guide

Requirement Recommended Grade
General purpose, cost-sensitive PA6
High temperature (>120°C) PA66, PA46
Wet/humid environment PA12, PA11
Maximum stiffness PA66-GF30/50

Modified Nylon Grade and Supply Review

Nylon Plastic supplies unfilled and modified PA compounds, with primary article and product support centered on pure PA, PA-GF20, and PA-CF30 routes. Grade review should include the drawing, service conditions, required approvals, annual volume, color, and incumbent specification.

Common Nylon Grade Selection Mistakes

  • Writing only “nylon” or “PA” on the drawing without identifying the matrix and modification.
  • Comparing dry tensile values while the production part will operate in humid or conditioned service.
  • Increasing fiber content before checking whether the real problem is geometry, gate position, weld lines, or creep.
  • Choosing CF30 for maximum stiffness when a GF20 compound already meets the functional requirement at lower cost and processing risk.
  • Assuming a flame, ESD, heat-stabilized, or approved formulation from the family name instead of the exact grade documentation.

Nylon Grade RFQ Checklist

A complete inquiry should identify the preferred PA matrix, reinforcement percentage, annual volume, drawing revision, color, molding process, service temperature, humidity, chemicals, impact, load duration, dimensional state, and regulatory requirements. Include the incumbent grade and failure mode when the request is a replacement project. This information allows the supplier to compare unfilled PA, GF20, GF30, and CF30 without relying on a generic strength ranking.

How Nylon Plastic Reduces Grade-Selection Risk

Buyers often receive quotations that list a resin family but omit the exact modification, conditioning state, or approval package. Nylon Plastic has worked across material modification and finished-product manufacturing since 2005, allowing one project review to connect grade selection with the intended molding, CNC, or 3D-printing route.

  • Product focus: pure PA, PA-GF20, and PA-CF30 can be compared as distinct commercial routes.
  • Custom compounding: formulation review is available when standard grades do not meet stiffness, impact, color, wear, flame, or dimensional requirements.
  • Manufacturing feedback: gate direction, machining deformation, moisture conditioning, or print orientation can be considered before material approval.
  • Buyer documentation: the RFQ can define TDS, COA, compliance, sample, incoming inspection, and lot-approval expectations before volume ordering.

Frequently Asked Questions

Should I choose PA6 or PA66 for injection molding?

PA6 often provides a broader processing window and good toughness, while PA66 is commonly selected for higher strength and thermal margin. Moisture, impact, geometry, approvals, and exact grade data can change the decision.

When should an unfilled nylon grade be replaced with GF20?

Consider GF20 when the unfilled grade cannot meet deflection, creep, shrinkage, or loaded-temperature targets. Validate impact, weld lines, warpage, surface appearance, and tool wear before approval.

What is the difference between GF20 and CF30 nylon?

GF20 uses approximately 20% glass fiber and is generally a more cost-effective moderate reinforcement. CF30 uses approximately 30% carbon fiber and targets higher specific stiffness, lower thermal expansion, or electrical behavior, depending on the formulation.

What must a nylon grade RFQ include?

Include the PA matrix, reinforcement or modification, drawing, volume, service temperature, humidity, chemicals, load, impact, tolerances, color, flame rating, and regulatory requirements.

Related Reading

Request a Nylon Grade Review

Send the drawing, current material, target properties, annual volume, and operating environment. We can compare the matrix and modification separately before recommending unfilled PA, GF20, GF30, or CF30.

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